Electrostatic experiments don't work very well under humid conditions. Some books state that the water vapor in the air makes the air conductive. Wrong. In reality the problem is caused by the liquid water that becomes adsorbed on surfaces of objects.
In order to make the air conductive, we'd have to fill it with movable charged particles. Evaporated water is not made of charged particles (ions,) instead it's made of neutral molecules, so the high humidity does not significantly affect the conductivity of the air. Even suspended water droplets (fog) does not significantly affect conductivity. For fog to be conductive, the individual droplets would have to posess an electric charge.
However, during humid conditions most insulators develop a surface layer of conductive water mixed with contaminants (including dissolved salts which makes this layer of water conductive.) If you find that you can't separate any charges by rubbing a balloon on your head, it's because the humid air has made the balloon and the hair very slightly damp. The air remains nonconductive, but surfaces of insulators become conductive when damp. Conductive surfaces don't separate any opposite charges when rubbed together. Cure this by warming them (drying them) with a blow-dryer. If a pair of insulators is sufficiently dry, it will "generate charge" even under very humid conditions. If conductive air were the culprit, this cure couldn't work
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